Comparison of Ahmad-Rolfes-Stepto theory, rate theory and Monte-Carlo modelling of gel point and network modulus
β Scribed by S. Dutton; H. Rolfes; R.F.T. Stepto
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 504 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0032-3861
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π SIMILAR VOLUMES
The signiΓcant contributions of Stepto to the development and understanding of gelation in non-linear random polymerizations are brieΓy reviewed. As an example, the recent AhmadΓRolfesΓStepto theory is used to interpret experimental gel points in stoichiometric polyurethane network-forming systems b
We demonstrate that the Monte Carlo evaluation of a phase-space integral is a viable alternative to the more computationally expensive classical trajectory surface-hopping method for calculating unimolecular electronic predissociation rate constants. Rate constants for NzO( 'Z+ ) +N2( 'Z: ) +O('P) c