Comparison of 9-Phenylfluorenyl and Triphenylmethyl in the Decomposition of Azo Compounds 1a,b
β Scribed by Cohen, Saul G.; Cohen, Fredric; Wang, Chi-Hua
- Book ID
- 126799263
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 804 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
In photochemically, electrochemically and thermally initiated decomposition, compounds containing the azo group (1RNxN2R) usually form reactive, short-lived radicals and which corresponds to synchro-1R~2R~, nous splitting. As examples, aliphatic azo compounds, 1-aryl-2-alkylazo compounds, azophospho
## Abstract Splitting constants and __g__ values are reported for 5,5βdimethylpyrrolidine 1βoxide spin adducts with radicals such as substitutedβPhΛ, NaSO~3~Λ, PhS~2~Λ, and others observed in the photochemical decomposition of azo compounds in various solvents.