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Comparison between high temperature UV-visible spectroscopy and electrochemistry for the in situ study of redox equilibria in glass-forming melts

✍ Scribed by J.-Y Tilquin; P Duveiller; J Glibert; P Claes

Book ID: 117148604
Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 157 KB
Volume: 224
Category: Article
ISSN: 0022-3093
DOI: 10.1016/s0022-3093(97)00476-6

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Oxygen interaction of CdS-based gas sens

Oxygen interaction of CdS-based gas sensors with different stoichiometric compositions was studied by X-ray photoelectron spectroscopy (XPS) and thermal-desorption mass spectroscopy observations combined with conductivity measurements. Three different types of film with different atomic ratios of Cd/S were used in the study of oxygen chemisorption in a low-temperature range between 300 and 570 K. Spray pyrolysis was used for the deposition of the films on glass substrates; XPS and energy dispersive spectroscopy of X-ray together with atomic force microscopy and scanning electron microscopy were used for the characterization of the composition and structure of the films. It was possible to distinguish different temperature ranges for the thermal desorption of the different adsorbed oxygen species. A comparison of the data from XPS and mass-spectroscopy observations with conductance measurements allows to conclude that metallic surface atoms are responsible for different interactions of oxygen species with CdS surfaces.

📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 379 KB