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Comparing thermal and mechanochemical decomposition of ammonium paratungstate (APT)

✍ Scribed by Maryam Sadat Marashi; Jalil Vahdati Khaki; Seyed Mojtaba Zebarjad


Book ID
113656644
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
387 KB
Volume
30
Category
Article
ISSN
0263-4368

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The potential for microwave decomposition of solid crystalline ammonium paratungstate (APT) and ammonium metatungstate (AMT) was investigated. It was observed that APT and AMT interact with \(2.45-\mathrm{GHz}\) microwave radiation. Samples of ammonium paratungstate ( \(20-50 \mathrm{~g}\) ) were su

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## Abstract The bulk structural evolution during the decomposition of ammonium paratungstate (APT) under various oxidizing and reducing gases was elucidated by the complementary techniques, in situ XAS, in situ XRD, and TG/DSC, combined with mass spectrometry. In the temperature range from 300 to 6