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Comparing the Reactivity of Benzenedithiolate- versus Alkyldithiolate-Bridged Fe2(CO)6 Complexes with Competing Ligands

✍ Scribed by Daniel Streich; Michael Karnahl; Yeni Astuti; Clyde W. Cady; Leif Hammarström; Reiner Lomoth; Sascha Ott

Book ID: 102165630
Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 418 KB
Volume: 2011
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.201001152

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✦ Synopsis

The reactivity of [(μ-X 2 bdt)Fe 2 (CO) 6 ] [(bdt)1, X 2 bdt = 3,6-disubstituted bezenedithiolate; X = H, Cl] with ligands of different donor strengths is investigated and compared to that of [(μ-pdt)Fe 2 (CO) 6 ] [(pdt)1, pdt = propyldithiolate] and [(μedt)Fe 2 (CO) 6 ] [(edt)1, edt = ethyldithiolate]. Strong donor ligands (L = CN -, PMe 3 ) when added to (bdt)1 lead to mononuclear [(bdt)Fe(L) 2 (CO) 2 ], (bdt)6(L), in a disproportionation

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