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Comparative study of tris(trifluoromethyl)phosphine oxide, tris(nonafluorobutyl)phosphine oxide and fluorobis(nonafluorobutyl)phosphine oxide with ammonia and amines

✍ Scribed by Mahmood, Tariq; Bao, Jian Ming; Kirchmeier, Robert L.; Shreeve, Jean'ne M.


Book ID
126289298
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
576 KB
Volume
27
Category
Article
ISSN
0020-1669

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Treatment of tris(2-pyridyl)phosphine or tris(2-pyridyl)phosphine oxide with electrophiles such as chlorine, bromine, deuterium chloride, or benzenediazonium chloride gave unusual coupling products, i.e., 5-chloro-, 5-bromo-, 5-deuterio-, or 5-phenylazo-2,2Јbipyridyls, respectively, as a major coupl