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Comparative study of physical and chemical activation modes. The case of the synthesis of β-amino derivatives

✍ Scribed by Gérard Jenner

Book ID
103399417
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
554 KB
Volume
52
Category
Article
ISSN
0040-4020

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## Abstract The reaction of (+)‐car‐2‐ene (**4**) with chlorosulfonyl isocyanate (=sulfuryl chloride isocyanate; ClSO~2~NCO) led to the tricyclic lactams **6** and **8** corresponding to the initial formation both of the tertiary carbenium and __α__‐cyclopropylcarbenium ions (__Scheme 2__). A numbe