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Comparative studies in the Cp[2(η2-S2) H series (Cp = t-BuC5H4, C5Me Et; M = Nb, Ta) on the reactivity of hydrie and disulfide ligands

✍ Scribed by Jean-Claude Leblanc; Claude Moise; Florence Volpato; Henri Brunner; Günther Gehart; Joachim Wachter; Bernhard Nuber


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
475 KB
Volume
485
Category
Article
ISSN
0022-328X

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The Influence of the Ligands Cp*(η5-C5Me
✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,