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Comparative stuctural studies of CIS and trans-CrF2(NH3)4+ cation with the x-ray method

✍ Scribed by J.V. Brenčič; B. Čeh; I. Leban


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
65 KB
Volume
16
Category
Article
ISSN
0022-1139

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✦ Synopsis


Trans-[CrF2(NH3)4']J.H20 and cis-[CrF2(NH3)47.


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Asymmetric salt effects on anion/cation
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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__