𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Comparative analysis of the transfer of alkaline and alkaline-earth cations across the water/1,2-dichloroethane interface

✍ Scribed by S.A. Dassie; L.M. Yudi; A.M. Baruzzi

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
620 KB
Volume
40
Category
Article
ISSN
0013-4686

No coin nor oath required. For personal study only.

✦ Synopsis

The transfer of alkaline and alkaline-earth cations across the water/l,Zdichloroethane interface in presence of l,lO-phenanthroline (phen) in the organic phase was studied using cyclic voltammetry in a concentration range wide enough to cover the following experimental conditions: C,,,(w) B C,,,(o) and C,,,(o) % C,.+(w).

The results obtained (when C,.+(w) ti C,,,,(o)) were compared with the theoretical voltammetric criteria reported by Homolka[l] for facilitated transfer. It appears that the transfer of all these cations occurs uia a facilitated mechanism. The stoichiometry of all complexes formed in the organic phase is also reported. The stability constants for Ca*+ -phen and Sr*+-phen complexes were estimated and compared with the tendency observed in the transfer potentials of these cations.

πŸ“œ SIMILAR VOLUMES

Mechanism of Transfer of a Basic Drug ac
Mechanism of Transfer of a Basic Drug across the Water/1,2-Dichloroethane Interface: The case of quinidine
✍ FrΓ©dΓ©ric Reymond; Hubert H. Girault; Guillaume Steyaert; Pierre-Alain Carrupt; B πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 German βš– 880 KB

## Abstract The electrochemical transfer of quinidine across the H~2~O/1,2‐dichloroethane interface was investigated by cyclic voltammetry, so as to determine its lipophilicity. The formal transfer potential was measured as a function of the pH of the aqueous phase. Both singly and doubly protonate

Mechanism of the Transfer of Alkali- and
Mechanism of the Transfer of Alkali- and Alkaline-Earth-Metal Ions across the Nitrobenzene-Water Interface Facilitated by Hexa- and Octaethylene Glycol Dodecyl Ethers
✍ Takashi Kakiuchi πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 383 KB

Transfer of \(\mathrm{Li}^{+}, \mathrm{Na}^{+}, \mathrm{K}^{+}, \mathrm{Rb}^{+}, \mathrm{Ca}^{2+}, \mathrm{Sr}^{2+}\), and \(\mathrm{Ba}^{2+}\) ions facilitated by hexa- and octacthylene glycol monododecyl ethers (C12E6 and C12E8) has been studied at the nitrobenzene (NB)water (W) interface using cy