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Communications: The Formation of Nitrile Imines in the Thermal Breakdown of 2,5-Disubstituted Tetrazoles

✍ Scribed by Huisgen, Rolf; Seidel, Michael; Sauer, Juergen; McFarland, James; Wallbillich, Guenter


Book ID
121880741
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
239 KB
Volume
24
Category
Article
ISSN
0022-3263

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The enol-imine to keto-enamine tautomeri
✍ E. J. Kikta Jr; J. F. Bieron πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 624 KB

## Abstract The formation of 3‐benzylamino‐5,5‐dimethylcyclohex‐2‐enone has been found to proceed through the initial formation of its enol‐imine tautomer. The enol‐imine has been isolated by a novel synthesis. It involves suspending dimedone in hexane for one hour at 67 Β°C with the amine in soluti