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Communications- Stereo-chemistry of the Claisen Rearrangement

✍ Scribed by Marvell, Elliot; Stephenson, John

Book ID: 126219767
Publisher: American Chemical Society
Year: 1960
Tongue: English
Weight: 120 KB
Volume: 25
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01074a629

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## Abstract Regiospecific addition of benzeneselenenyl bromide to ethyl vinyl ether followed by alcoholysis of the initially formed β‐bromoalkyl selenide **1** by primary, secondary or tertiary allylic alcohols **2a‐e** gave the mixed acetals **3a‐e**. Subsequent oxidation and thermal treatment of