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Communications- Electrophilic Substitution of 1,3-Dichloroazulene

✍ Scribed by Anderson, Jr., Arthur; Replogle, Lanny

Book ID: 126860564
Publisher: American Chemical Society
Year: 1960
Tongue: English
Weight: 113 KB
Volume: 25
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01077a038

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## Abstract Pentadienyllithium **(16)** was regioselectively and efficiently transformed to 1‐trimethylsilyl‐2,4‐pentadiene **(17)** by reaction with chlorotrimethylsilane (__Scheme 5__). Deprotonation of **17** and subsequent electrophilic attack furnished the regioisomeric products **12** and/or