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Communications - Base-Catalyzed Rearrangement of α-Haloacetanilide into α-Anilinoacid Derivatives

✍ Scribed by Sarel, Shalon; Greenberger, Aliza


Book ID
126835667
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
247 KB
Volume
23
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES


Metal ion - base catalyzed rearrangement
✍ Stan S. Hall; Albert Poet 📂 Article 📅 1970 🏛 Elsevier Science 🌐 French ⚖ 107 KB

We have observed that a-ketohemimercaptals, formed (2) by equilibrating a-ketoaldehyde mrmohydrates with thiols (3), rearrcmge exceedingly slowly in the presence of one equivalent of sodium ocetote (180 h) and somewhat faster in the presence of an equivalent of a tertiary amine (4) such as N-methylp