Communications. A Convenient Synthesis of Alkyl Halides from Carboxylic Acids
โ Scribed by Cristol, Stanley; Firth, Jr., William
- Book ID
- 120549674
- Publisher
- American Chemical Society
- Year
- 1961
- Tongue
- English
- Weight
- 125 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
by basic hydrolysis is the standard method to prepare cyclopropene carboxylic acidst2). We have found, however, that if the cyclopropene resulting from the initial addition has a benzylic hydrogen adjacent to the ring, the alkaline hydrolysis condition lead instead to methylenecyclopropane acids. T
A general, mild, and convenient method has been developed for the synthesis of various alkyl and aryl sulfinic acid salts and sulfonamides from the corresponding halides. Key to the success of this methodology is the design and facile synthesis of sodium 3-methoxy-3-oxopropane-1-sulfinate (SMOPS), a