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Comments on the transport coefficients of dense hard core systems

✍ Scribed by Yaakov Rosenfeld


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
137 KB
Volume
48
Category
Article
ISSN
0009-2614

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✦ Synopsis


The Davis, Rice aud Set:gets theory for the tramport coefficients of the square well fluid disagrees with the moleculardynamics results of Alley and Alder. The effects on the transport coefficients of dense hard core systerrs, upon adding an attractive part of the potential, axe discussed in terms of the corresponding effects on the entropy.

In an attempt to extend

Enskog's theory to a model system capable of having a liquid state, Davis, Rice and Sengers (DRS) considered [ 1 ] a fluid composed of particles interacting via the square well (SW) potential. The DRS expressions for the coefficients of selfdiffusion, D, and shear viscosity, rl, using both Monte-Carlo [2] and approximate [3] values for the radial distnbuUon function g(r), we.e examined in view of the high density molecular dynamics transport data of Alley and Alder [4]. Define the relative ch: age in D and T/upon adding the attractive well to a t~rd sphere (I-IS) potential at a given density, p, and temperature, T:


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