Electron transfer rates in the levich an
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W. Schmickler; W. Vielstich
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Article
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1973
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Elsevier Science
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English
⚖ 489 KB
The Levich and Dogonadze theory of redox reactions in solutions is regarded as a suitable model to discuss the nature of quantumeffects in electron transfer. In Section I the quantum mechanical framework-first order perturbation theory and the Born-Oppenheimer approximation-is reviewed; an inaccurac