We report high-resolution infrared vibrational-rotational spectra of the weakly bound complexes N 2 O-H 2 O and N 2 O-D 2 O in the higher frequency N 2 O stretching mode region (ν 3 = 2223.756693(124) cm -1 ). The measurements were carried out using a free jet expansion in combination with a lead sa
Comments on the high resolution photoelectron spectrum of H2O and D2O
✍ Scribed by L. Åsbrink; J.W. Rabalais
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 276 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The photoelectron spectra of Hz0 and D20 have been measured with stificient resolution to partially resolve: rotitionsl structure. The similarity between the band resu!h from the photoelectron position to theground ion$ state, ?B,, and one of the molecular Rydberg transitions is discilssed. Some of the factors effect& the rest-l&on in photoclrctron spesrroswpy are presznral.
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The microwave spectrum of the formaldehyde -water complex ( CH 2 O -H 2 O ) has been studied with a pulsedbeam Fourier transform Fabry -Perot cavity spectrometer. Both a-type and b-type transitions were observed for each of the isotopic species studied. To provide additional structural information,
The high resofution photoelectron spectrum of CS has been obtained. Ionization potrntkds are found nt 11.34 (Xk), 17.78 (A\*lB, 15.83 (Bzc) and 18.03 (C'X) eV, and a spin-orbit bT;plitting of 278 cm-' is observed on the second band.