A set of non-lmear cqustlons LS given winch solves the stationary Schrodmgcr equalion III terms of a known subproblem. An ItemlIve solution of the equations ylclds the degenerate version of Raylegh-SchrBdmgcr perturbation theory, but olhcr approxunatlon schemes, as well as a purely numerIca solullon
✦ LIBER ✦
Comments on the convergence of the ordinary Rayleigh-Schrödinger perturbation expansion
✍ Scribed by Reinhart Ahlrichs
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 145 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
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## Rayleigh-Schr6dinger variational pertxhation theory is applied to the hydrogen-like atom with a perturbation proportional to l/r. It is r&orousIy shown &t the e.xact eigenfunction is obtained by direct summation of the perturbation ezqansion through infinite order.