Comments on “reactions of excited and ground state H3+ ions with simple hydrides and hydrocarbons”
✍ Scribed by Vincent G. Anicich; Jean H. Futrell; Wesley T. Huntress Jr.; J.K. Kim
- Publisher
- Elsevier Science
- Year
- 1975
- Weight
- 127 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0020-7381
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Metastable excited CI' was recently reported by Rakshit in a study using the Aberystwyth SIFT apparatus. We conclude that this report refers to a mixture of Cl+ and HCl+, and that the results are hence erroneous. Our recent work using the same apparatus gives no evidence for excited Cl+.
## Abstract The potential energy surface for the reaction of the ground‐state carbon atom [C(^3^P~j~)] with the propargyl radical [HCCCH~2~(X^2^B~1~)] is investigated using the G2M(RCC,MP2) method. Numerous local minima and transition states for various isomerization and dissociation pathways of do