๐”– Bobbio Scriptorium
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Comments on prof. Noyes' review

โœ Scribed by Robinson, R.


Book ID
102886195
Publisher
Wiley (John Wiley & Sons)
Year
1934
Weight
699 KB
Volume
53
Category
Article
ISSN
0368-4075

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โœฆ Synopsis


thiit clicmiciil reiict.ioiis iirc ii very iiiisiifc giiirlc for dist.inguisliiiig l)et\-ccii clcctro-iilciit~ iiiitl coviileiit. coiiipoiiiids. Sodium iodide is untloiil)tctlly elect,rovnlcnt and inctliyl iodide coviilcnt., h i t tlicrc is i i o 'nppitrtvit diffcrcwce Iiotwccii their rciictioiis with silver iiitriitc in alcoliolic solut.ioiis except tliiit eotliiiiri iogidc gives rlcctroviiloiit sodiririi iiitrittc iiiid iiicthyl iodiclc, co.iilt!iit, iiictliyl iiitrittc. Ail iiiinlogoris rciiinrk iiiiiy I)c riiiitle of iiii iittciiipt to follow the rritctioiis of tiiutoiiiorio coiiipouiiils iiritl of corijugiitccl cloiil)lc coviilciiws. 'I'lic rwctioii:: slioiild be ciircfiilly studied I)ut the cvitlciicc~ froin rerrctioiis shnultl hi! rciiifnrct!tl by ii coiisidcriit ion of liliy::iCiil proj)e*rtics. the octet rule ciiiplinsizetl by I'rof. liohiiisoii, the rulv for coiiiplcsions given irbovc, coiitliictiiiic-c ofsolut ions. dipole iiioniciits, Siigdeii's IiiiriicIior, iit)sorptioii spcctrii, crystiilliiic strrictiirv. boiliag poiiits iiiirl niclting points, iiioleciiliir weiglits in soliitioii iiii11 :is n gas, rind opticiil activity.

111 IS75 'l'horpc, on the 1i:isk of' tlw iiiolcciilitr voliiiiii, of pliosplioriis osyliloritlr, ooiicliitltrd that it hiis thv striii!tiirt! lJ--O--('l i i i d t h i i t t111: pliesphorirs is trivirlcwt . I ~I ~. s ; ~I I coiitciitlccl tliiit tliv structure is 0 2= P-CI, with t l w pliosplioriis qiiiiicliiv-\riileiit. Siiic-c sciiii-ioiiic osygeii ntoiiis Iii~vc I)coi kiiowi, piirtly on t h basis of the priiclior, \ve ciiii S ~C thiit ciicli \viis 1):irtIy riglit tiiill I)iirtlY ~roiig. ' I ' l i ~ ,PI \ " : I , , " I ' . CI -.. A:cl structure isiiliiicJ.~t.cicrtitiiily :O: 1' : C1. 'I'li(b pliospliorus * -:el is tctriic:oviilciit iiiitl uiii-ioiiic.viilc~iit. Iicr~iscri found t1iii.t ozow converts pliosplioriis tricliloritlc to tIic oxychloritlc. 'I'Iiis is siiiiilitr to thc recent. discovery (Scliiiiiinclicr iiiid Sprciigw, %. nriorg. nllgcvn. Clrcmic, 1!)29, 182, 139) tlrirt OZIJIIC . .-:o: . * + . . converts nitrosyl clilorirlc to iiitryl cliloriclc, C1 : S : 0. 111 110111 ciises iiii oxygen iitoiii scpiirirtcs froill t Iic ozone with six clect.roiis rind unites with n piiir of iiiisliiirctl clcctroiis, giving ii sciiii-ioiiic lrriioii iiiid th11 iiitrogcii niid pliospliorus I)CCOIIIC tctriico'iileiit iiiitl


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