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Comments on phosphorescence decay times of benzene and methyl-benzene derivatives

✍ Scribed by J.W. Rabalais; H.J. Maria; S.P. McGlynn

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
190 KB
Volume
3
Category
Article
ISSN
0009-2614

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✦ Synopsis

It is shown that methyl substitution in benzene increases (T. v-mixing to an extent which is readiLy observable in the intrinsic phcsphorescence lifetime. It is also shown that C-H vibrational modes which are esternal to the benzene ring (i. e. in the CH3 group) contribute to phosphorescence quenching-Fina&. some recently reported 'relaxation effects ' are shown to be caused by poor temperature controls.

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