## Abstract The formation of the new compounds of L‐alanine alaninium nitrate and L‐alanine sodium nitrate has been presented with adequate explanation with the aid of the FTIR, XRD and NLO measurements as a reply to “Comments on papers reporting IR‐spectra and other data of alleged L‐Alanine Alani
Comments on papers reporting IR-spectra and other data of alleged L-alanine alaninium nitrate and L-alanine sodium nitrate crystals
✍ Scribed by M. Fleck; A. M. Petrosyan
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 112 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0232-1300
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✦ Synopsis
Abstract
We argue that the IR‐ and Raman‐spectra of “L‐alanine alaninium nitrate” given in “Investigation on the growth, optical behaviour and factor group of an NLO crystal: L‐Alanine Alaninium nitrate” by Aravindan et al., Cryst. Res. Technol. 42, 1097 (2007), actually concern L‐Alanine. Correspondingly, the data presented in “A comparative study on the growth and characterization of nonlinear optical amino acid crystals: L‐Alanine (LA) and L‐alanine alaninium nitrate (LAAN)” by Aravindan et al., Spectrochim. Acta A 71, 297 (2008), seems to be erroneous, as is “Synthesis, Growth, and Characterization of a New Semiorganic Nonlinear Optical Crystal: L‐Alanine Sodium Nitrate (LASN)”, Sethuraman, et al., Cryst. Growth Des. 8, 1863 (2008). In these papers properties and data were reported for L‐Alanine compounds that actually are L‐Alanine crystals and, in addition, unit cell parameters were given that seem to have been copied from other papers. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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## Abstract Amino acid family crystals exhibit excellent nonlinear and electro‐optical properties. L‐alanine alaninium nitrate (LAAN) single crystal belonging to the amino acid group was grown by slow cooling solution growth technique. The High resolution X‐ray diffraction (HRXRD), Fourier transfor