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Comments on “A smog chamber and modeling study of the gas phase NOx-air photooxidation of toluene and the cresols”

✍ Scribed by J. P. Killus; G. Z. Whitten

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
191 KB
Volume
13
Category
Article
ISSN
0538-8066

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Reply to “comments on ‘a smog chamber an
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✍ W. P. L. Carter; R. Atkinson; A. M. Winer; J. N. Pitts Jr. 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 138 KB

Recently Killus and Whitten [l] commented on our experimentall modeling study of the gas-phase NO, -air photooxidation of aromatics to the effect that they did not believe that unknown radical sources exist in smog chambers, despite the fact that we [2,3] and others [4] find it necessary to include

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Rate constants for the gas-phase reactions of OH radicals with β-dimethylstyrene and acetone. Mechanism of ββdimethylstyrene NOx – air photooxidation
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The rate constants of gas-phase reactions of the hydroxyl radical with 0-dimethylstyrene and acetone have been determined by a relative method at 298 K. The values obtained are P-dimethylstyrene (3.3 f 0.5) X lo-" cm3/molecule-s and acetone (6.6 f 0.9) X cm3/ molecule-s. A simplified kinetic treatme