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Comment on the strongest type of hydrogen bond

✍ Scribed by Paul A. Giguere

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
275 KB
Volume
80
Category
Article
ISSN
0009-2614

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✦ Synopsis

Ab initio studies of hydrogen bonding in the carboxylic acid-fluoride systems apply to the free state. In condensed phases strong interactions lead to more complex structures. IR spectra of saturated solutions and solid solvates indicate at least two different types of hydrogen bond. The high solvation energy of the fluoride anion enables different ionic and molecular species to coexist.

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