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Comment on the papers of T. Matsushima and M. Enyo:: Studies on the mechanism of the hydrogen electrode reaction by means of deuterium tracer, I–III

✍ Scribed by J.C. Reeve

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
84 KB
Volume
20
Category
Article
ISSN
0013-4686

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Studies on the mechanism of the hydrogen
Studies on the mechanism of the hydrogen electrode reaction by means of deuterium tracer—I. the reaction route
✍ T. Matsushima; M. Enyo 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 839 KB

The reaction route of the hydrogen electrode reaction on Ni, Rh, Au, and Pt at the reversible potential was investigated through the exchange reaction between deuterium and light water. Various reaction routes involving hydrogen adatom H(a) and adsorbed hydrogen molecule-ion H;(a) as the reaction in

Studies on the mechanism of the hydrogen
Studies on the mechanism of the hydrogen electrode reaction by means of deuterium tracer—II. The reaction mechanism
✍ T. Matsushima; M. Enyo 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 580 KB

The exchange reaction bctwccn deuterium gas and light water was conducted with Ni, Rh, and Pt catalyst. Through analysis of isotopic composition of the gaseous hydrogen during the exchange reaction, the exchange rates of the individual steps, H2 s 2H(a) and H(a) + B Z+ H+B + r, of the hydrogen elect

Studies on the mechanism of the hydrogen
Studies on the mechanism of the hydrogen electrode reaction by means of deuterium tracer—III. The stoichiometric number
✍ T. Matsushima; M. Enyo 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 580 KB

The stoichiometric number of the hydrogen electrode reaction on Rh, Ni, Pt, Au, Ag, and Ir was determined by means of deuterium tracer at the reversible potential. It is shown that, along with the change of the rate-determining step in the reaction route, H, $2H(a) followed by H(a) + B z$ H+B + e, w

Elementary reaction rates of the hydroge
Elementary reaction rates of the hydrogen electrode reaction on nickel analyzed by means of deuterium tracer—I the anodic region
✍ T. Matsushima; M. Enyo 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 689 KB

The exchange reaction between deuterium gas and light water was conducted with a nickel electrode under anodic polarization. The rates of the constituent steps of the hydrogen electrode reaction were determined at various anodic overpotentials through analysis of the isotopic composition of the hydr