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Comment on “the origin of anomalous bond dissociation energies of V+(H2)n clusters”

✍ Scribed by P.R. Kemper; J.E. Bushnell; P. Maitre; M.T. Bowers

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 403 KB
Volume: 242
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00684-v

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✦ Synopsis

In a recent study, we reported experimental determinations of bond dissociation energies and entropies for V+(H2)n (n = 1 to 6) and suggested that a spin change from quintet to triplet occurs upon addition of the sixth H 2 ligand. A very recent theoretical paper by Niu et al. disputes this and concludes that the experimental results are consistent with purely quintet clusters (J.

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