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Comment on “the effect of reagent rotation on steric requirements of elementary exchange reactions” by H. Kornweitz, A. Persky and R.D. Levine

✍ Scribed by Howard R. Mayne; Judith A. Harrison

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
98 KB
Volume
133
Category
Article
ISSN
0009-2614

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✦ Synopsis

The conclusion that reagent rotation in 0 + HCl enhances reactivity at high impact parameter, but suppresses reactivity at low impact parameter has been examined. It is found instead that rotation enhances reactivity as effectively for low as for high impact parameter.

📜 SIMILAR VOLUMES

The effect of reagent rotation on steric
The effect of reagent rotation on steric requirements of elementary exchange reactions
✍ H. Kornweitz; A. Persky; R.D. Levine 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 603 KB

The body-fixed coordinate system appears to be particularly suited for discussing the role of reagent rotation. The simple picture provided by the jr-conserving approximation accords with the available evidence and with specially performed trajectory computations for the 0 + HCl (u = 0, i) and 0 + D