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Comment on a paper by Nobuyuki Nakai and M. L. Jensen, “The kinetic isotope effect in the bacterial reduction and oxidation of sulfur”

✍ Scribed by H.R. Krouse

Book ID
118882848
Publisher
Elsevier Science
Year
1965
Tongue
English
Weight
250 KB
Volume
29
Category
Article
ISSN
0016-7037

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Rates of oxidation of XCOO-(X = H, D) by Brz in acid aqueous media were measured between 274 and 332 K. The derived Arrhenius parameters for both reactions log k ~( M -l S-') = (11.81 f 0.10) -(14.33 f 0.13)/0 log ~D ( M -' S-') = (13.77 f 0.13) -(17.62 f 0.04)/0 where 0 = 4.575T X kcal/mol, with (