Combustion Synthesis of Transition Metal Carbosulfides

✍ Scribed by Pablo Wally; Masanori Ueki

• Book ID: 102974825
• Publisher: Elsevier Science
• Year: 1998
• Tongue: English
• Weight: 605 KB
• Volume: 138
• Category: Article
• ISSN: 0022-4596
• DOI: 10.1006/jssc.1998.7779

✦ Synopsis

The combustion synthesis of ternary and quaternary carbosulfides of the transition metals was investigated to obtain highpurity materials to be tested as solid lubricants in high-temperature environments. The main carbosulfide formation mechanisms have been clarified in the case of the technologically interesting tantalum carbosulfide, enabling the preparation of reaction products with controlled purity. The formation of molten tantalum sulfide as an intermediate product was found to play a key role for obtaining a homogeneous reaction product, and the presence of excess carbon reduced the oxygen content of the carbosulfide. However, the higher the overall carbon contents, the higher is the amount of carbide impurities in the reaction products. Use of iodine or hexachlorobenzene as a catalyzer minimized the need of excess sulfur in the raw powder mixture, reduced the amount of carbide impurities, and contributed to the homogenization of the reaction products.