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Combustion studies on ammonium perchlorate/trimethylammonium perchlorate mixtures

โœ Scribed by S.R. Jain; K.C. Adiga; V.R. Pai Verneker


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
395 KB
Volume
45
Category
Article
ISSN
0010-2180

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โœฆ Synopsis


A study of the burning rates of compressed mixtures of ammonium perchlorate (AP) and trimethylammonium perchlorate (TMAP) has been carried out at ambient pressure. The overall increase in the linear burning rate, showing a maximum at a composition having 80% TMAP, has been discussed in terms of factors such as stoichiometry, presence of faster burning component, and eutectic melt formation. The thermal decomposition studies of the mixtures, using isothermal thermogravimetry and differential thermal analysis techniques, indicate the possibility of eutectic melt formation.


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Effect of trimethylammonium perchlorate
โœ K.C. Patil; M. Ramanath; V.R. Pai Verneker ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 271 KB

Addition of trimethylammonium perchlorate to potassium perchlorate (KP) catalyzes its thermal decomposition. However, although the additive sensitises KP-PU propellant decomposition, its combustion is desensitised. The observed effects have been explained in terms of the role played by the early for