Combustion energies and standard molar enthalpies of formation for the complexes of the first-row transitional metal chlorides withL-α-histidine
✍ Scribed by Shengli Gao; Sanping Chen; Xuwu Yang; Qizhen Shi
- Book ID
- 105728214
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 256 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1001-6538
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Complexes have been prepared by the reactions of 2,2'-biquinoline with the chlorides of cobalt, nickel and copper in ethanolic solution. The complexes have stoichiometry MLCI, where M = Co'+, Nil+, Cu\*+ and L is 2,2'-biquinoline. The cobalt and copper complexes have tetrahedral structures while the
The chloro complexes of cobalt, nickel and copper with 2-phenyl-4-quinoline carboxylic acid have stoichiometry MLCI 2 . The complexes which are polymeric have a stereochemistry in which the metal ion is in a six coordinate environment. The decompositions of the complexes have been studied by thermog
new DfH°m (GeS,cr,298.15 K) obtained in Part II of this study (J. Chem. Thermodynamics 1994, 26, 727), yield several derived results for DfH°m(GeS2,cr,298.15 K) that are in reasonable agreement with the calorimetric determinations. The standard molar enthalpy of the transition: GeS2(vit) = GeS2(cr):