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Combining Designer Cells and Click Chemistry for a One-Pot Four-Step Preparation of Enantiopure β-Hydroxytriazoles

✍ Scribed by Wiktor Szymanski; Christiaan P. Postema; Chiara Tarabiono; Florian Berthiol; Lachlan Campbell-Verduyn; Stefaan de Wildeman; Johannes G. de Vries; Ben L. Feringa; Dick B. Janssen

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 160 KB
Volume: 352
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201000502

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✦ Synopsis

Abstract

The multistep catalytic process using designer cells, either added as freshly prepared suspensions or as stable lyophilized powder, and click reaction can be performed in one pot. The sequence of four reactions allows the production of both enantiomers of β‐hydroxytriazoles with high enantiomeric excess.

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