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Combined pulse microcatalytic and ESR studies of butylene oxidation on V-Mg oxide catalysts

✍ Scribed by Simakov, A. V. ;Veniaminov, S. A.


Book ID
112695737
Publisher
Springer
Year
1985
Tongue
English
Weight
267 KB
Volume
28
Category
Article
ISSN
0133-1736

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An on-line electron spin resonance (ESR) technique was applied to investigate the oxidation states of the metallocene catalysts CpTiCl 3 , CpZrCl 3 , Cp 2 TiCl 2 , and Cp 2 ZrCl 2 . These metallocene catalysts were activated by modified methylaluminoxane (MMAO). It was found that the titanocene cata