The utility of bis(tributyltin)oxide-bromine for the selective oxidation of secondary hydroxyl groups in the presence of primary hydroxyl groups has been further demonstrated by the efficient conversions of D-mannitol into r+fructose and 1,5-dideoxy-1,5-imino-D-mannitol Cl-deoxymannojirimycin).
Combined action of an enzyme and a metal catalyst on the conversion of d-glucose/d-fructose mixtures into d-mannitol
β Scribed by Michiel Makkee; Antonius P.G. Kieboom; Herman van Bekkum
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 564 KB
- Volume
- 138
- Category
- Article
- ISSN
- 0008-6215
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Consecutive catalytic oxidation (oxygen, D-galactose oxidase), dehydration (L-proline) and reduction (hydrogen, palladium) of methyl b-D-galactoside in water at neutral pH yielded methyl 4-deoxy-6-aldehydo-b-D-glucoside without intermediate recovery steps demonstrating the potential power of a multi
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