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Combinatorial Synthesis of Bimetallic Complexes with Three Halogeno Bridges

✍ Scribed by Sébastien Gauthier; Laurent Quebatte; Rosario Scopelliti; Kay Severin

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
319 KB
Volume
10
Category
Article
ISSN
0947-6539

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✦ Synopsis

Abstract

Methods for the synthesis of bimetallic complexes in which two different metal fragments are connected by three chloro or bromo bridges are reported. The reactions are general, fast, and give rise to structurally defined products in quantitative yields. Therefore, they are ideally suited for generating a library of homo‐ and heterobimetallic complexes in a combinatorial fashion. This is of special interest for applications in homogeneous catalysis. Selected members of this library were synthesized and comprehensively characterized; single‐crystal X‐ray analyses were performed for 15 new bimetallic compounds.

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## Abstract The 1:1 reaction of the diacetyl monoxime‐2‐pyridyl hydrazone HL^1^ (1) and the pyridine‐2‐carboxaldehyde‐2‐imidazoline hydrazone hydrobromide HL^2^ (2) with copper(II) sulfate pentahydrate in methanol affords a series of new sulfate‐bridged dimeric copper(II) complexes, [Cu^II^~2~(HL^1