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Colour reaction of phenols with the gibbs reagent. The reaction mechanism and decomposition and stabilisation of the reagent

✍ Scribed by Svobodová, D. ;Křenek, P. ;Fraenkl, M. ;Gasparič, J.


Publisher
Springer-Verlag
Year
1977
Weight
567 KB
Volume
67
Category
Article
ISSN
0344-838X

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## Abstract The mechanism of the reaction under discussion has been established by investigating the products of the reaction between 2,4‐bis(4‐methoxyphenyl)‐1,3,2,4‐dithiadiphosphetane 2,4‐disulfide (Lawesson’s reagent, LR) and __N__‐alkylhydroxamic acids HAs **1**. The primary intermediate is an