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Color Centers in the Near Infrared Region in Crystals MFX (M = Ba, Sr; X = Cl, Br)

โœ Scribed by Wei Zhao; Yan-Ming Mi; Zeng-Fu Song; Mian-Zeng Su


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
187 KB
Volume
103
Category
Article
ISSN
0022-4596

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โœฆ Synopsis


Color centers with absorption bands in the near infrared region (peaking near (900 \mathrm{~nm}) ) in (\mathrm{X})-rayed (M \mathrm{~F} X) crystals have been found. They might be attributed to the aggregates of (F\left(X^{-}\right))centers which are similar to (M) centers in (M X) crystals. The interconversion among (F\left(\mathrm{~F}^{-}\right), F\left(\mathrm{Br}^{-}\right)), and (M) centers in (\mathrm{BaFBr}) crystals has been found. These aggregated color centers are stable and exhibit stimulable absorption bands in the region from 700 to (1000 \mathrm{~nm}). Therefore some solid state lasers can be used as stimulating light sources instead of He-Ne lasers for reading the information stored in PSL image plates made of these X-ray storage phosphors. (\mathcal{O} 1993) Academic Press. Inc.


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Ba3Te2O6X2 is obtained by reacting TeO2 in a BaX2 flux at 1000 ยฐC under atmospheric conditions. The samples are characterized by powder and single crystal XRD. All four compounds crystallize in the cubic space group Fd3m with Z = 16. The structures consist of a rigid โˆž 3 [M3Te2O6] 2+ framework (M: S