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Colloidal Synthesis of Non-Equilibrium Wurtzite-Type MnSe

✍ Scribed by Ian T. Sines; Rajiv Misra; Peter Schiffer; Raymond E. Schaak

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
310 KB
Volume
122
Category
Article
ISSN
0044-8249

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Manganese chalcogenides exhibit a variety of important magneto-optical properties that collectively result from their crystal structures, the large number of unpaired electrons in high-spin Mn 2+ , bandgaps that span visible to ultraviolet wavelengths, and interesting magnetic ordering schemes. [1]

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The elusive wurtzite polymorph of MnSe, the end member of the magnetic solid semiconductor solution Zn 1-x Mn x Se, was synthesized for the first time as colloidal nanoparticles. In their Communication on page 4638 ff., R. E. Schaak et al. describe the chemical low-temperature synthesis of this prev

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Moderate concentrations of a small non-adsorbing polymer cause a suspension of colloidal particles to phase-separate into coexisting colloidal fluid and crystal via the 'depletion' mechanism. At higher polymer concentrations, crystallization is suppressed, and a variety of non-equilibrium aggregatio