𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Collisional quenching of iodobenzene ion one-photon photofragmentation

✍ Scribed by Robert C. Dunbar

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
353 KB
Volume
115
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The one-photon photorhssoclauon of mdobenzene IOII at 5145 run IS quenched to a substantial extent by Ion-neutral colbs~ons at pressures III the 1O-6-1O-5 Torr range. This mdxales rhat a major fraction of the ion populauon Mates wtb rates less than or of the order of lo2 s-' The quenchmg results are m accord wth quaweqtibnum theory calculabons Remterpretanon of threshold photodlssonauon data III the l&t of t.h~s colhslonal quenchmg leads to a heat of formation of 1135 kJ mol-' for phenyl cation.

πŸ“œ SIMILAR VOLUMES

Study of collisional relaxation of ions
Study of collisional relaxation of ions by two-photon photodissociation
✍ Myung S. Kim; R.C. Dunbar πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 357 KB

Collisional relaxation of bromobenzene molecular ion by several neutral molecules has been measured by a two-photon photodissociation method. This new technique allows 2 quantitative estimation of energy loss in the relaxation process. Collisional relaxation rates have been found to be much slower

Kinetic studies on state-state coupling
Kinetic studies on state-state coupling and collisional quenching of excited sulfur dioxide
✍ Qun Zhang; Congxiang Chen; Shuqin Yu; Xingxiao Ma πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 155 KB

The time-resolved total emission of SO 2 at were moni-1 1 (B B : X A ) 354.9 nm 1 1 tored following the direct excitation by a laser pulse. A three-level model was proposed 266 nm to deal with SO 2 (X 1 A 1 , A 1 A 2 , B 1 B 1 ) system. From a kinetic treatment of these measurements, the coupling co