Collisional deactivation of vibrationally highly excited polyatomic molecules. II. Direct observations for excited toluene
โ Scribed by Hippler, H.
- Book ID
- 111926819
- Publisher
- American Institute of Physics
- Year
- 1983
- Tongue
- English
- Weight
- 858 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.444670
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Energy removed from highly vlbratlonally excited polyatomic molecutes by polyatomic co&ion partners decreases with increasmg number of atoms in the hot molecule. The trend is qualitatively predicted by two quasi-statistical modek of energy transfer, and calculations of energy removal by the transitt
The influence of the population distribution function on the collisional relaxation of highly vibrationally excited polyatomic molecules is analyzed in a non-reactive system. Unimodal and bimodal energy distributions are considered. Calculations made with unimodal energy distributions showed that th