Collision theory of bimolecular and unimolecular reactions and its experimental test
โ Scribed by S. G. Christov
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 119 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract An exact collision theory of unimolecular and bimolecular gas phase reactions is derived from a general quantumโmechanical formulation of reactions rates based on the assumption that the reactants are in thermal equilibrium. In this way the quantum corrections to the classical collision
## Abstract The mechanism of the collisionโinduced fragmentation of peracetylated methylโฮฑโDโglucopyranoside was investigated using deuteriumโlabelled acetates and sequential mass spectrometry. Loss of the substituent at C(1), the anomeric carbon, yields an ion of __m/z__ 331, [C~14~H~19~O~9~]^+^.
The cyclopentadienyl radical decomposition has been studied in detail by high-level correlation MO methods combined with multichannel RRKM rate constant calculations. The product channels of the reaction were examined by calculating their pressure-dependent branching rate constants. The overall reac
In practical applications such as combustion studies, prediction of the pressure dependence of unimolecular reaction steps is made more difficult by the great variety of conditions (pressure, temperature and composition) arising in the medium. A general scheme for the treatment of pressure dependenc