Collision-induced electronic relaxation in polyatomic vapors
โ Scribed by A.E.W. Knight; C. Parmenter
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 99 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0047-2670
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๐ SIMILAR VOLUMES
in this note we comment on recent steady state kineticannlyses of coLICon induced intersystem crossing in gases and sugest an alternative description of the intia-and intermolecular dynamics. \* In ref. [8] the singbt-triplet mking is ascribed to ztn RXternal (collisional) heavy atom effect; see a
## Close -coupling scattering cakulations are shown to be a significant improvement over the Born approximation for collision frequencies of low energy electrons in water v.xpor and it is argued that further improvement will necessitate a more refined model of the interaction.
A theory IS presen:ed for vlbratmnai energy relavatlon m polyatomlc molecular hquids mduced by Cor~ohs mteractlons, and applied to sereral bnear trlatomic molecules III mert solrents The predIcted rates are conststent with experImenta measurements on these systems.