Collision-induced dissociations of deprotonated α-amino acids. The occurrence of specific proton transfers preceding fragmentation

Effect of the position of a basic amino

Effect of the position of a basic amino acid onC-terminal rearrangement of protonated peptides upon collision-induced dissociation

✍ Gonzalez, Javier; Besada, Vladimir; Garay, Hilda; Reyes, Osvaldo; Padron, Gabrie 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 632 KB

Internal rearrangement involving the loss of the C-terminal amino acid residue upon collision-induced dissociation (CID) or metastable decomposition was studied for protonated peptides. To investigate the structural characteristics of peptides responsible for this rearrangement, a series of syntheti