Two theoretical models, a reorganization model and an activation model, are presented for accurately determining the energy barrier of the type Ž . 2qr3q M H O of the transition-metal complexes in the electron-transfer process. Ab initio 2 6 Ž . 2qr3q calculations are carried out at UMP2r6-311G leve
✦ LIBER ✦
Collision energy- and spin-orbit coupling-dependence of quenching probability in the electronic energy transfer reaction S(1D)+CO→S(3P)+CO(v,J)
✍ Scribed by Hiroto Tachikawa; Takayuki Hamabayashi; Manabu Igarashi
- Book ID
- 114143115
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 158 KB
- Volume
- 453
- Category
- Article
- ISSN
- 0166-1280
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Based on an activation model, a available scheme to calculate the rate of the electron-transfer reaction between transition-metal complexes in aqueous solution is presented. Ab initio technique is used to determine the electron-transfer reactivity of the type M(H 2 O) 2+/3+ 6 of transition-metal com