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Collection and Analysis of Trace Formic and Acetic Acid Vapors in Air Using Aminopropyl-Modified Surfaces

✍ Scribed by B.J. Johnson; S.C. Huang; A. Wong; L. Yao


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
337 KB
Volume
49
Category
Article
ISSN
0026-265X

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✦ Synopsis


Quartz filter surfaces were modified with aminopropyltrialkoxysilanes and used to collect gas phase acids. The filters were chemically characterized by titrimetric, gravimetric, and chromatographic methods; on the basis of these experiments, filter preparation methods were optimized. Analytical procedures for formic and acetic acids were developed based on their displacement from a sampled surface by a strong acid eluant and subsequent analysis of the eluant by ion chromatography. Passive collection of the acids from air and elution of the acids from the filter were highly efficient; in active sampling, efficiency of collection for acetic acid was less consistent than for formic acid. Analytical results from samples taken in Las Vegas are reported; concentration levels are consistent with previously reported values. (\mathcal{O} 1994) Academic Press. Inc.