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Co(III)-salen catalyzed carbenoid reaction: Stereoselective [2,3]sigmatropic rearrangement of S-ylides derived from allyl aryl sulfides

✍ Scribed by Tsutomu Fukuda; Tsutomu Katsuki

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 224 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00639-4

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✦ Synopsis

Allyi aryl sulfides and diazoacetic acid esters react in the presence of optically active Co(lll)salen complex (4) with good enantioselectivity, to give the [2,31sigmatropic rearrangement products, 2arylthio-3-aryl-4-pentenoic acid esters, via the corresponding S-ylides.

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