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Coherency of copper/sapphire interface studied by atomistic simulation and geometrical analysis

✍ Scribed by Sergey V. Dmitriev; Nobuhiro Yoshikawa; Yutaka Kagawa; Masanori Kohyama


Book ID
104202002
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
475 KB
Volume
542
Category
Article
ISSN
0039-6028

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✦ Synopsis


From experiment it is known that, for copper epitaxially grown on a-Al 2 O 3 (0 0 0 1) surface, the close-packed planes and the close-packed directions are parallel in the two crystals. In this work, we present the results of computer simulations based on a simple atomistic model assuming that sapphire is absolutely rigid. For the Cu-Cu interactions, both the Morse pair potential and the Rosato-Guillope-Legrand many-body potential were used. The interaction of copper with sapphire was described by means of the copper potential functions modified by introducing the two fitting parameters. We introduce a measure of the atomic coherency near the interface and study the change in coherency due to atomic relaxations. Results for the two mutual orientations are compared. Finally, using a method recently proposed by the present authors, we study coherency of interpenetrating copper and sapphire crystals as a function of the misorientation angle.