The Rates of SN2 Reactions and Their Rel
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Luisβ
G. Arnaut; SebastiΓ£oβ
J. Formosinho
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Article
π
2007
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John Wiley and Sons
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English
β 198 KB
π 1 views
## Abstract The energy barriers of symmetrical methyl exchanges in the gas phase have been calculated with the reaction path of the intersecting/interactingβstate model (ISM). Reactive bond lengths increase down a column of the Periodic Table and compensate for the decrease in the force constants,