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Cob(I)alamin als Katalysator 2. Mitteilung [1]. Reduktion von gesättigten Nitrilen in wasserfreier Lösung

✍ Scribed by Albert Fischli


Publisher
John Wiley and Sons
Year
1978
Tongue
German
Weight
578 KB
Volume
61
Category
Article
ISSN
0018-019X

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✦ Synopsis


Cob (I)alamin as Catalyst 2. Communication [1]. Reduction of Saturated Nitriles in Anhydrous Solution

Using cob (I)alamin as homogenous catalyst in glacial acetic acid saturated nitriles are reduced following the path of a reductive amination. The results prove the presence of an intermediate imine during the reduction of saturated nitriles with cob (I)alamine.


📜 SIMILAR VOLUMES


Cob (I)alamin als Katalysator 4. Mitteil
✍ Albert Fischli 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 691 KB

## Abstract **Cob(I)alamin as Catalyst. 4. Communication. Reduction of α,β‐Unsaturated Nitriles** Using catalytic amounts of cob (I)alamin and an excess of metallic zinc as source of electrons 1‐naphthonitril (**5**) has been reduced to (1‐naphthyl)methylamin (**6**) and in small amounts to (1‐nap

Cob (I)alamin als Katalysator. 3. Mittei
✍ Albert Fischli; Daniel Süss 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 636 KB

**Cob (I)alamin as Catalyst 3. Communication [1]. Examination of an Enantioselective Reduction Using α,β‐Unsaturated Esters** α,β‐Unsaturated esters can be reduced to the corresponding saturated esters using catalytic amounts of cob (I)alamin in the presence of an excess of zinc. An enantioselectiv